Relaxation dynamics in the strong chalcogenide glass-former of Ge22Se78

نویسندگان

  • Pengfei Li
  • Yaqi Zhang
  • Zeming Chen
  • Peng Gao
  • Tao Wu
  • Li-Min Wang
چکیده

The enthalpy relaxation is performed in the glassy Ge22Se78 to understand the dynamic behaviors. The structure of the glass is examined by X-ray diffraction and Raman spectra. The dynamic parameters such as the fragility, stretching exponent and non-linear factor are determined. A low fragility of m = 27 is exhibited for the chalcogenide, however, the stretching exponent is found not to have a larger value. The enthalpy relaxation spectra are constructed for various glass formers, and a relationship between the fragility and the symmetry of the spectra is demonstrated. The dynamic results are used to evaluate the structure of the Ge22Se78 glass.

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عنوان ژورنال:

دوره 7  شماره 

صفحات  -

تاریخ انتشار 2017